직/편성물 염색

STABILITY AND REVERSIBILITY OF THE DYE-CELLULOSE BOND FOR VINYLSULFONYL REACTIVE DYEINGS.

  • 출판일1992.05
  • 저자
  • 서지사항
  • 등록일 2016.11.02
  • 조회수 306
The alkaline hydrolysis of 11 vinylsulfonyl (VS) reactive dyes (F-type) fixed on cellulose was examined at 50 degrees Centigrade and pH 10.9. The reversibility of the dye-fiber bond was verified by the cylindrical-film-roll method using dyed and undyed cellophane. The F-types decomposed to yield the VS types, which were further hydrolyzed to yield the hydroxyethylsulfonyl types or reacted with cellulose to re-form the F-types. The F-types were composed of two species, presumed to arise from the initial VS reaction with cellulose 6-OH or 2-OH, which showed fast and slow rates of bond scission.