비의류제품

Effect of water and acrylonitrile on apparent melting behavior of polyacrylonitrile copolymer (Japanese)

  • 출판일1998.08
  • 저자
  • 서지사항
  • 등록일 2016.11.02
  • 조회수 484
The effect of water and acrylonitrile (AN) on apparent melting temperature of acrylonitrile/methylacrylate copolymer (PAN) wa investigated. Apparent melting temperature of PAN decresed with increasing water content and saturated at 150℃, at which water content was 25 wt% to PAN. The water content corresponded to the molar ratio between water and the CN group in PAN was 1:1. When a mixture of water and AN (70/30 by weight) was added to PAN, apparent melting temperature continously decreased. Monophase PAN melt was obtained at a molar ratio of the CN group in PAN/AN/water = 2/1/2.